First of all, welcome to the forum!
Second of all, here is your answer --
Importing Windows Live Hotmail Contacts to Microsoft Outlook
1) Log into your Windows Live Hotmail account and click the "Contacts" button.
2) Click "Export Contacts" and click "Export Contacts" again. Click "Save" and select a folder to which to save the exported contacts. Select a location such as the desktop to allow you quicker access to the file. Click "Save." The Windows Live Hotmail contacts are exported and saved as a WLMContacts.csv file.
3) Import the Windows Live Hotmail contacts to Microsoft Outlook. To do so, launch Microsoft Outlook and click the "File" button. Click "Import and Export."
4) Click "Import from another program or file" and click "Next." Click "Comma separated values (DOS)" and click "Next."
5) Click "Browse" and select the "WLMContacts.csv" file containing the Windows Live Hotmail contacts. Click "OK" to import it to Microsoft Outlook.
6) Choose the option you want to use to process any duplicate contacts already in your Microsoft Outlook address book. Click "Next" and click "Finish."
Synchronizing Microsoft Outlook Contacts to your iPod
1) Connect your iPod to the computer using the supplied USB cable and launch iTunes if it does not launch automatically. iTunes displays your iPod on the left panel under "Devices."
2) Click your iPod and click the "Info" tab. Click the "Sync contacts with/from" check-box. Select "Outlook."
3) Click "All Contacts" if you want to sync all the Microsoft Outlook contacts. Alternatively, click "Selected groups" and select the imported Windows Live Hotmail contacts you want to sync from Microsoft Outlook. Click "Apply." The Windows Live Hotmail contacts you exported to Microsoft Outlook are synchronized to your iPod.
Now putting on Moderaor's cap....
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