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. . .You can't do it directly on the mail app, if you have an smtp account you can. . .
The Archangel
twerppoet said:IMAP or Exchange accounts will sync mail folders with the server. POP accounts won't. SMTP (Simple Mail Transfer Protocol) is a protocol/server most most providers use to handle outgoing mail, and is standard for both IMAP and POP accounts.
The IMAP and POP protocols have to do with handling mail syncing/copying between a computer client and the server. SMTP sends your email on it's way to the recipient; although that is probably a gross over simplification it will have to do, because thats about all I understand about it myself.